This is a good idea. BUT,I can think of lots of "side effects" to it..
Mostly technical..A great percentage of estate radio equipment is
obsolete,broken,needing unavailable parts, etc. New hams are not
usually interested in books,tech data ,construction tools ,material
etc.sad but true..Some radio clubs will take estates and sort them out
,direct the items to someone that will appreciate them..A radio club
would be my suggestion.. good luck..W4PQW