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#1
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Having recently obtained a 1930's two-pole knife
switch an a porcelain base, I decided to make use of it in my own shack. Seeming to be of copper, on inspection it proved to be copper-plated brass. The rivets forming the hinge on the knives were loose and could not be banged-up so I drilled them out and replaced with 2BA screws plus locknuts. So, now I can earth the G5RV when it is not in use, and disconnect it from the TX. It brought up something interesting, and that is, that one half of the G5RV produced no signal on RX - perhaps in the recent winds when the lilac tree blew over (Quod Vide), one of the connections from the co-ax to the ladder sections has fractured; that remains for investigation. This is thin coax which has been installed for about 22 years. I was intrigued to find that both the braid and the inner conductor were blackened, despite being on a section of the cable that could not have had water ingress. Perhaps is time to replace with some larger diameter coax? |
#2
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On Tue, 1 Feb 2005 10:40:22 -0000, Airy R.Bean wrote:
This is thin coax which has been installed for about 22 years. I was intrigued to find that both the braid and the inner conductor were blackened, despite being on a section of the cable that could not have had water ingress. The problem is not '(liquid) water ingress' but diffusion of water molecules from the atmosphere through the cable sheathing. Perhaps is time to replace with some larger diameter coax? The cable sheathing may not be that much thicker than that of the 'thin' coax, and so will not significantly slow the diffusion, and in addition you will have mechanical problems due to the much heavier coax. Your thin coax probably blackened years ago. You can try to reduce the effect by covering the cable sheathing with a light coating at regular time-intervals of something water-resistant such as wax furniture spray or WD40 - not as '(liquid) water' is the problem, but that the light fractions of the wax or oil will tend to fill the pores in the sheathing material and so delay the diffusion effect. You could move to the Arctic or a desert of your choice ;-) -- from Aero Spike |
#3
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![]() "Spike" wrote in message ... On Tue, 1 Feb 2005 10:40:22 -0000, Airy R.Bean wrote: This is thin coax which has been installed for about 22 years. I was intrigued to find that both the braid and the inner conductor were blackened, despite being on a section of the cable that could not have had water ingress. The problem is not '(liquid) water ingress' but diffusion of water molecules from the atmosphere through the cable sheathing. Perhaps is time to replace with some larger diameter coax? The cable sheathing may not be that much thicker than that of the 'thin' coax, and so will not significantly slow the diffusion, and in addition you will have mechanical problems due to the much heavier coax. Your thin coax probably blackened years ago. You can try to reduce the effect by covering the cable sheathing with a light coating at regular time-intervals of something water-resistant such as wax furniture spray or WD40 - not as '(liquid) water' is the problem, but that the light fractions of the wax or oil will tend to fill the pores in the sheathing material and so delay the diffusion effect. You could move to the Arctic or a desert of your choice ;-) -- from Aero Spike ================================= A not-very-well-remembered true story. Shortly after WW2, a British Post Office cable ship was repairing (or stealing for reparations) a coaxial telephone cable in the North Sea, somewhere off the Heligoland Bight. It had been manufactured and laid by our European friends, the Germans, during the war. The cable was polyethylene plus air insulated. The inner conductor was insulated by a thick, circular, polyethylene string or rod, slowly spiralling around it. Plenty of air space. There may not have been an outer conductor - the return conductor could have been the North Sea water. It's OK up to a few KHz. But the whole thing was protected by a thick polyethylene sheath in contact with sea water. Polyethylene was a very uncommon material in those days. ( It has always amazed me how much time communications engineers had to spare in experimenting in the middle of a world war. The Russians experimented with future, peacetime, high-voltage DC, single-wire power transmission while the population was dying by the million from murder, starvation and disease. I obtained some of my programs' formulae for calculating the resistance of ground electrodes from a translated Russian book of the time.) The above-mentioned unbroken cable was laid across the deck of the ship. The cable jointer, not knowing quite what to expect, had his tools around him, including a lighted parafin blow lamp. The cable jointer, a skilled workman, cut into the sheath with a saw. And immediately there was a hissing noise and a very hot flare of pale flame. Whether the jointer was injured or not is lost in history. ( I was either in Hong Kong at that time or was walking the darkened pavements in Hiroshima marvelling at the lighter-coloured shadows cast on the paving slabs by the first of the WMD.*) It later transpired in the laboratory that when water is under relatively high pressure, such as at the bottom of the North Sea, when in contact with a thick polyethylene membrane it dissasociates into hydrogen and oxygen. The very light element diffuses through leaving heavy oxygen on the outside. Thus, after a few years, the air-space on the inside becomes filled with high pressure hydrogen. If there's any copper on the outside then presumably it becomes blackened by copper oxide. A tongue-in cheek WARNING - When digging up very old air-spaced coax from soggy soil in your back yard it is advisable to erect no-smoking notices. ( * Actually, the RAF, of which I was a member, had already incinerated more people than both atomic bombs just in one fire storm on one city. Churchill might have been knighted for services rendered. But Air Marshall Bomber Harris was never decorated with a medal or honoured with a statue. He, partially responsible, with 10,000 air-crew plus 100,000 ground staff, took the ashamed blame. After all, there are very few problems in finding 100,000 people to manufacture and operate and transport 5 million people to the gas chambers.) I'm on South African red wine tonight. It says on the bottle it should be drunk within 12 months of purchase and within two days of opening. I have a corkscrew. No problems! Help yourself to a program. ---- .................................................. .......... Regards from Reg, G4FGQ For Free Radio Design Software go to http://www.btinternet.com/~g4fgq.regp .................................................. .......... |
#4
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"Spike" wrote in message
... On Tue, 1 Feb 2005 10:40:22 -0000, Airy R.Bean wrote: This is thin coax which has been installed for about 22 years. I was intrigued to find that both the braid and the inner conductor were blackened, despite being on a section of the cable that could not have had water ingress. The problem is not '(liquid) water ingress' but diffusion of water molecules from the atmosphere through the cable sheathing. Perhaps is time to replace with some larger diameter coax? The cable sheathing may not be that much thicker than that of the 'thin' coax, and so will not significantly slow the diffusion, and in addition you will have mechanical problems due to the much heavier coax. Your thin coax probably blackened years ago. You can try to reduce the effect by covering the cable sheathing with a light coating at regular time-intervals of something water-resistant such as wax furniture spray or WD40 - not as '(liquid) water' is the problem, but that the light fractions of the wax or oil will tend to fill the pores in the sheathing material and so delay the diffusion effect. You could move to the Arctic or a desert of your choice ;-) For thin (RG58 etc) coax, it is cheap and running it not normally and issue- so just replace every 12 mths or so (it really does not like the sun!). For RG213, run inside new hose pipe (B&Q cheap stuff is ideal). Seems to last 'forever'- well over 10 years without visible deteriotion of the coax, or measureable change in loss at 430MHz. Not so much about saving money as hassle lowering masts etc to replace. -- Brian Reay www.g8osn.org.uk www.amateurradiotraining.org.uk FP#898 |
#5
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On Tue, 1 Feb 2005 19:43:27 +0000 (UTC), Reg Edwards wrote:
I was either in Hong Kong at that time or was walking the darkened pavements in Hiroshima marvelling at the lighter-coloured shadows cast on the paving slabs by the first of the WMD A nice story of the perils of new materials technology, Reg, thanks. If the SA red hasn't taken it's toll, do a little Googling on "Japanese occupation of Manchuria" + Harbin. See if you can find the appropriate meaning of the Japanese word "maruta". -- from Aero Spike |
#6
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"Reg Edwards" wrote in message
... It later transpired in the laboratory that when water is under relatively high pressure, such as at the bottom of the North Sea, when in contact with a thick polyethylene membrane it dissasociates into hydrogen and oxygen. The very light element diffuses through leaving heavy oxygen on the outside. Thus, after a few years, the air-space on the inside becomes filled with high pressure hydrogen. What caused this "disassociation", and where did it happen? Just, I'd expect the hydrogen to bubble off PDQ, assuming this process did occur. Also, diffusion is the movement of something from a high to a low concentration, assuming the mechanism is correct, I wonder how long before the concentration would equalise (after all, the hydrogen around the cable must have been in pretty low concentration. Was the cable sealed at the ends? If so, what happened the gas (I assume air) already in the cable? If there's any copper on the outside then presumably it becomes blackened by copper oxide. How did get to the copper? If the insulation was all polyethylene, how did it sometimes stop the oxygen and not others? Is Dr Boris around? -- Brian Reay www.g8osn.org.uk www.amateurradiotraining.org.uk FP#898 |
#7
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On Tue, 1 Feb 2005 20:02:07 -0000, "Brian Reay"
wrote: For thin (RG58 etc) coax, it is cheap and running it not normally and issue- so just replace every 12 mths or so (it really does not like the sun!). With the best will in the world, I can't follow that Brian! Jock. -- "You teach a child to read, and he or her will be able to pass a literacy test". - George W. Bush, Townsend, TN, Feb 2001 . |
#8
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Reg, I am a teetotaler myself but that was quite a story. Cheers from the
other side of the pond........ WB7FFI "Reg Edwards" wrote in message ... I'm on South African red wine tonight. It says on the bottle it should be drunk within 12 months of purchase and within two days of opening. I have a corkscrew. No problems! Help yourself to a program. |
#9
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On Tue, 1 Feb 2005 22:00:22 -0000, "Brian Reay"
wrote: "Reg Edwards" wrote in message ... It later transpired in the laboratory that when water is under relatively high pressure, such as at the bottom of the North Sea, when in contact with a thick polyethylene membrane it dissasociates into hydrogen and oxygen. The very light element diffuses through leaving heavy oxygen on the outside. Thus, after a few years, the air-space on the inside becomes filled with high pressure hydrogen. What caused this "disassociation", and where did it happen? Water dissociates naturally to a small extent. Think of how the pH scale is derived. Just, I'd expect the hydrogen to bubble off PDQ, assuming this process did occur. Also, diffusion is the movement of something from a high to a low concentration, assuming the mechanism is correct, I wonder how long before the concentration would equalise (after all, the hydrogen around the cable must have been in pretty low concentration. It all sounds a bit like Maxwell's 'demons' but my half-educated guess is that the polyethylene was acting as a semi-permeable membrane, allowing only the much smaller hydrogen atoms (ions?) to pass through under the action of the pressure differential. |
#10
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"Custos Custodum" wrote in message
... On Tue, 1 Feb 2005 22:00:22 -0000, "Brian Reay" wrote: "Reg Edwards" wrote in message ... It later transpired in the laboratory that when water is under relatively high pressure, such as at the bottom of the North Sea, when in contact with a thick polyethylene membrane it dissasociates into hydrogen and oxygen. The very light element diffuses through leaving heavy oxygen on the outside. Thus, after a few years, the air-space on the inside becomes filled with high pressure hydrogen. What caused this "disassociation", and where did it happen? Water dissociates naturally to a small extent. Think of how the pH scale is derived. I thought the pH scale came from "per Hydronium"- H30+ ? If the 'extra' H came from the water, then there would also be OH- to neutralise it. Just, I'd expect the hydrogen to bubble off PDQ, assuming this process did occur. Also, diffusion is the movement of something from a high to a low concentration, assuming the mechanism is correct, I wonder how long before the concentration would equalise (after all, the hydrogen around the cable must have been in pretty low concentration. It all sounds a bit like Maxwell's 'demons' but my half-educated guess is that the polyethylene was acting as a semi-permeable membrane, Semi-permeable membranes feature in osmosis, rather than diffusion (although I have heard osmosis related to diffusion in via the concept of the solvent diffusing ). allowing only the much smaller hydrogen atoms (ions?) to pass through under the action of the pressure differential. As I recall, a hydrogen ion doesn't stay 'free' for long. Long time since I did Chemistry, is Dr Boris not about? -- Brian Reay www.g8osn.org.uk www.amateurradiotraining.org.uk FP#898 |
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